June 5, 2013

Physicists at the U.S. Department of Energy’s Ames Laboratory have discovered surprising changes in electrical resistivity in iron-based superconductors. The findings, reported in Nature Communications, offer further evidence that magnetism and superconductivity are closely related in this class of novel superconductors.

“We found that the directions of smallest and largest resistivity  within the conducting layers are significantly dependent on the  composition of the compounds, and in some compositions, they change  sign, or, in other words, electric current flows easier in the direction  that was originally more difficult” said Ames Laboratory faculty  scientist Ruslan Prozorov. “This change can only be explained if the  underlying magnetic behavior is intimately connected to  superconductivity.”

Understanding the basic physics behind  iron-based superconductivity may someday make it possible to use them  for super-efficient energy technologies.

Erick Blomberg, an Ames Laboratory graduate research assistant,  spearheaded the research under the guidance of Prozorov and Ames  Laboratory scientist Makariy Tanatar. The team studied resistivity in  barium-iron-arsenide compounds with different chemical substitutions,  which allowed for probing electronic properties throughout the entire regime in which magnetism and superconductivity coexist.

In conventional superconductors, magnetism and superconductivity do not coexist and one suppresses another. In contrast, some iron-based superconductors show significant overlap between magnetism and superconductivity, which allows for unique measurements of their properties in the coexistence region.

“But there is a complication,” said Prozorov, who is also an Iowa State University professor in the Department of Physics & Astronomy. “In the coexistence region, the crystal structure of barium-iron-arsenide crystals is such that the crystal splits into the structural domains (also known as structural twins), which makes studying directional electronic properties difficult.

To eliminate the structural domains, the team developed a technique in which single crystals are physically pulled apart. A sample is suspended by wires in a horseshoe-shaped bracket, which can be mechanically stretched. This assembly is then placed into a small liquid helium cryostat to reach temperatures where magnetism and superconductivity coexist. Polarized optical microscopy is used to distinguish between different structural domains to verify that the samples are in the detwinned (without fragmented domains) state. Electric resistivity is then measured.

Blomberg and colleagues studied a series of samples, covering a precise range of compositions, provided by Nanjing University’s Hai-Hu Wen.

“In this case, making chemical substitutions was, in effect, taking electrons away from the compound or adding electrons to the compound,” said Blomberg, who will soon receive a PhD in condensed matter physics from Iowa State University. “And as you take electrons away, at a certain point the direction in which it was harder for electricity to flow becomes the direction it was easier for it to flow.”

Theoretical predictions made by physicists Jörg Schmalian and Rafael   Fernandez (both former Ames Laboratory scientists) along with Naval   Research Lab’s Igor Mazin and Michelle Johannes, closely matched the   experimental findings.

(left to right) Erick Blomberg, Makariy Tanatar and Ruslan Prozorov.

The research is supported by the U.S.   Department of Energy Office of Science. DOE’s Office of Science is the   single largest supporter of basic research in the physical sciences in   the United States, and is working to address some of the most pressing   challenges of our time. For more information, please visit the Office of   Science website at science.energy.gov/.

The Ames Laboratory is a U.S. Department of Energy Office of Science national laboratory operated by Iowa State University. The Ames   Laboratory creates innovative materials, technologies and energy   solutions. We use our expertise, unique capabilities and   interdisciplinary collaborations to solve global problems.